Product ID:ETHANOL BLENDS, GASOHOL
MSDS Date:02/22/1991
FSC:9130
NIIN:01-090-1092
MSDS Number: BRPGL

FARMLAND INDUSTRIES, INC

PETROLEUM DIVISION
KANSAS CITY, MO 64116
US

Emergency Phone: 816-459-4100 OR 316-251-4000

Info Phone: 816-459-4100

Preparer: DAVID R. SCHONAUER

Cage: 6G072

FARMLAND INDUSTRIES,INC.,BULK PERTOLEUM PROD DIV.

7305 KANSAS CITY, MO 64116-0005 US

Telephone: 316-251-4000, CHEMTREC 800-424-9300

Cage: 6G072

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <20%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <20%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <6%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <3%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 12%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9293

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE*IS IRRITATING TO BODY TISSUES.
INHALATION OF VAPOR CAUSES CNS EFFECTS. INGESTION CAUSES G/I
EFFECTS AND MAY LEAD TO ASPIRATION INTO THE LUNGS.
CHRONIC*CONTAINS BENZENE (SEE CARCINOGENICITY) AND SOME HIGHT
BOILING HYDROCARBONS WHICH MAY BE CARCINOGENIC.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE:SLIGHT TO SEVERE IRRITATION. SKIN:POSSIBLE
IRRITATION; PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DERMATITIS.
INHALED:SIGNS OF INTOXICATION, DIZZINESS, RESPIRATORY IRRITATION.
INGESTED:G/I DISTRES S, CONVULSIONS, CYANOSIS, AND ASPIRATIONINTO
THE LUNGS DURING VOMITING WHICH CAN LEAD TO CHEMICAL PNEUMONIA.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING
DERMATITIS, RESPIRATORY ILLNESS, OR OTHER CONDITIONS WHICH HAVE THE
SAME SYMPTOMS OR EFFECTS AS STATED ABOVE.

First Aid:IF IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR. EYE:FLUSH
W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP & WATER. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALED:REMOVE TO
FRES H AIR. AID/RESTORE BREATHING IF NECESSARY. INGESTED:DO NOT
INDUCE VOMITING. GIVE 2 LARGE GLASSES OF MILK OR WATER TO DILUTE &
GET IMMEDIATE MEDICAL CARE. NOTHING BY MOUTH IF UNCONSCIOUS.

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA.
WATER MAY BE INEFFECTIVE ON FLAMES,USE SPRAY TO COOL NEARBY
CONTAINERS EXPOSED TO FIRE. WATER MAY ALSO SPREAD FIRE
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG GROUND OR FLOOR, THEN 'FLASH BACK' FROM A DISTANT
IGNITION SOURCE. GROUND CONTAINERS TO PREVENT STATIC IGNITION

Spill Release Procedures:NOTIFY EMEERGENCY RESPONSE PERSONNEL.
ELIMINATE INGITION SOURCES. EVACUATE NON-ESSENTIAL PERSONNEL.
CONTAIN SPILL. PREVENT RUN OFF TO SEWERS, STREAMS, ETC. NOTIFYFIRE
AUTHORITIES.
Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR.

Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN
TRANSFERRING BY GROUNDING EQUIPMENT. KEEP CONTAINERS CLOSED AND
AWAY FROM HEAT & IGNITION SOURCES! DO NOT PRESSURIZE
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. DO NOT SIPHON BY MOUTH. HANDLE, STORE, AND TRANSPORT PER OSHA
29CFR1910.106.

Respiratory Protection:APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR WHERE
EXPOSURE EXCEEDS ACCEPTABLE LIMITS. SUPPLIED AIR, OR SELF-CONTAINED
BREATHING APPARATUS (SCBA) REQUIRED FOR TNTRY INTO TANKS, VESSELS &
OTHER CONFINED SPACES.
Ventilation:PROVIDE ADEQUATE VENTILATION TO KEEP VAPORS BELOW
PERMISSABLE CONCENTRATIONS.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL GOGGLES OR FACESHIELD
Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING
WHERE SKIN CONTACT MAY OCCUR. FOR LOADING, UNLOADING, GAUGING, STAY
UP WIND.
Work Hygienic Practices:MFR: ? HMIS:USE GOOD INDUSTRIAL HYGIENE
PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING
OR DRINKING.
Supplemental Safety and Health
KEY2:KT MSDS INCLUDED PP1 OF MSDS FROM ASHLANT OIL WITH X DRAWN ACROSS
THE FRONT. ASHLAND IS PROBABLY THE MANUFACTURER, BUT SINCE THE
MSDS HAS FARMLAND'S NAME ON IT, ASHLAND IS LISTED AS THE VENDOR.

HCC:F1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:400 MM
Vapor Density:4
Spec Gravity:0.72
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:REDDISH GOLDEN BROWN LIQUID WITH GASOLINE ODOR.
ODOR THRESHOLD APPROX. 10 PPM.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HALOGENS, STRONG ACIDS, AND ALKALIS
Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAME, STATIC
ELECTRIC BUILD-UP AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CARON MONOXIDE, CARBON DIOXIDE AND
HYDROCARBONS
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED UNDER NORMAL
TEMPERATURES AND PRESSURES.

Waste Disposal Methods:RECYCLE AS MUCH RECOVERABLE PRODUCT AS POSSIBLE.
PLACE NON-RECOVERABLE MATERIAL IN CONTAINERS FOR DISPOSAL. DISPOSE
I/A/W FEDERAL, STATE & LOCAL REGULATIONS. HMIS SUGGESTS
INCINERATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.